What personal protective equipment (PPE) is essential for handling white phosphorus (WP)?

When handling white phosphorus (WP), the use of fire-resistant gloves and overalls is crucial due to WP's highly incendiary nature and its ability to cause severe burns upon contact with skin. White phosphorus ignites spontaneously in air and can ignite clothing or other materials, leading to serious injuries. Therefore, wearing specialized fire-resistant clothing helps protect the body from potential thermal injuries while handling this hazardous material.

In addition, fire-resistant gloves provide an extra layer of protection for the hands, which are particularly vulnerable during handling operations. While other types of PPE, such as chemical-resistant goggles, may be necessary for different hazardous materials, they are not specifically designed to address the unique risks associated with white phosphorus. The nature of WP necessitates the use of PPE that is equipped to withstand heat and fire, making fire-resistant gloves and overalls the essential choices for safe handling.